An eight-connected porous metal–organic framework based on hetero pentanuclear clusters†
Abstract
A new MOF based on hetero pentanuclear clusters, [(CH3)2NH2]1.66[Cd1.84Na0.66(BDC)3]·DMF·0.5EtOH (1), has been prepared. Iodine adsorption studies reveal that 1 can reversibly adsorb iodine. Furthermore, electrochemical impedance spectroscopy (EIS) of 1⊃I2 shows that it has a relatively high conductivity at room temperature.