Issue 3, 2014
From the journal:

CrystEngComm

Syntheses, structures and luminescence properties of three metal–organic frameworks based on 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid†

Hongming He,a   Fuxing Sun,*a   Hongmin Su,a   Jiangtao Jia,a   Qin Lic  and  Guangshan Zhu*ab  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, PR China
E-mail: zhugs@jlu.edu.cn
Fax: +86 431 85168331
Tel: +86 431 85168887

b Queensland Micro- and Nanotechnology Centre, Griffith University, Queensland 4111, Australia

c Environmental Engineering and Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan Campus, Queensland 4111, Australia

Abstract

Three metal–organic frameworks (MOFs), namely [Zn2(TPIA)(OH)(H2O)]·H2O (JUC-114), [Cd2(TPIA)(OH)(H2O)2]·H2O (JUC-115), and [Co2(TPIA)(OH)(H2O)2]·H2O (JUC-116) (JUC = Jilin University China), based on a new ligand, 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid (H3TPIA), were synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopy, TGA analysis and powder X-ray diffraction. JUC-114, JUC-115 and JUC-116 all possess 3D frameworks with (4,8)-connected fluorite (flu) topology based on similar tetranuclear metal centers as secondary building unit (SBU). Furthermore, the luminescence of the ligand H3TPIA and compounds was measured at room temperature.

Graphical abstract: Syntheses, structures and luminescence properties of three metal–organic frameworks based on 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid

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Article information

DOI
https://doi.org/10.1039/C3CE41764F
Article type
Paper
Submitted
03 Sep 2013
Accepted
28 Oct 2013
First published
30 Oct 2013

CrystEngComm, 2014,16, 339-343

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Syntheses, structures and luminescence properties of three metal–organic frameworks based on 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid

H. He, F. Sun, H. Su, J. Jia, Q. Li and G. Zhu, CrystEngComm, 2014, 16, 339 DOI: 10.1039/C3CE41764F

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