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Issue 83, 2016
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Synthesis and solid state structure of a metalloid tin cluster [Sn10(trip8)]

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Abstract

(trip2Sn)2 (trip = 2,4,6-i-Pr3C6H2) reacts with Mg(I) reductants (LMg)2 (L = HC[C(Me)N(dipp)]2) and (L′Mg)2 (L′ = HC[C(Me)N(mes)]2) with Sn–C bond cleavage and formation of the novel metalloid tin cluster Sn10trip8 1 or elemental tin. 1, which contains Sn atoms in the formal oxidation states 0, +I and +II, and the side products LMgtrip (2) and L′Mgtrip (3) were characterized spectroscopically and by single crystal X-ray diffraction.

Graphical abstract: Synthesis and solid state structure of a metalloid tin cluster [Sn10(trip8)]

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Supplementary files

Article information


Submitted
17 Aug 2016
Accepted
25 Aug 2016
First published
25 Aug 2016

This article is Open Access

Chem. Commun., 2016,52, 12282-12285
Article type
Communication

Synthesis and solid state structure of a metalloid tin cluster [Sn10(trip8)]

J. Wiederkehr, C. Wölper and S. Schulz, Chem. Commun., 2016, 52, 12282
DOI: 10.1039/C6CC06770K

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