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Issue 54, 2015
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Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

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Abstract

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.

Graphical abstract: Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

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The article was received on 06 Mar 2015, accepted on 02 Jun 2015 and first published on 03 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC01932J
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Citation: Chem. Commun., 2015,51, 10907-10909
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    Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

    S. C. E. Stieber, N. Huguet, T. Kageyama, I. Jevtovikj, P. Ariyananda, A. Gordillo, S. A. Schunk, F. Rominger, P. Hofmann and M. Limbach, Chem. Commun., 2015, 51, 10907
    DOI: 10.1039/C5CC01932J

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