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Issue 25, 2015
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Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

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Abstract

The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite 1(FeSe2) tetrahedral chains separated by Fe–amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.

Graphical abstract: Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

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Article information


Submitted
30 Oct 2014
Accepted
30 Nov 2014
First published
01 Dec 2014

Chem. Commun., 2015,51, 5355-5358
Article type
Communication
Author version available

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

J. T. Greenfield, C. Pak, S. Kamali, K. Lee and K. Kovnir, Chem. Commun., 2015, 51, 5355
DOI: 10.1039/C4CC08608B

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