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Issue 99, 2014
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Silver(I) and thallium(I) cations as unsupported bridges between two metal bases

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Abstract

Stirring Lewis-basic transition metal complexes with the salts M[BArCl4] (M = Ag, Tl; ArCl = 3,5-C6H3Cl2) resulted in the formation of diplatinum complexes [{(Cy3P)2Pt}2(μ-Ag)][BArCl4] (3) and [{(Cy3P)2Pt}2(μ-Tl)][BArCl4] (4) and the diiron compound [{(OC)3(Me3P)2Fe}2(μ-Ag)] (5) featuring bridging, unsupported metal cations. Their properties were investigated by multinuclear NMR spectroscopy, as well as X-ray diffraction and infrared measurements.

Graphical abstract: Silver(i) and thallium(i) cations as unsupported bridges between two metal bases

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Publication details

The article was received on 28 Oct 2014, accepted on 30 Oct 2014 and first published on 30 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC08508F
Citation: Chem. Commun., 2014,50, 15685-15688
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    Silver(I) and thallium(I) cations as unsupported bridges between two metal bases

    H. Braunschweig, R. D. Dewhurst, F. Hupp and C. Schneider, Chem. Commun., 2014, 50, 15685
    DOI: 10.1039/C4CC08508F

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