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Issue 97, 2014
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Germane vs. digermane formation

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Abstract

Oxidative addition reactions of dialkylchalcogenanes R2E2 and [Me2Si(Nt-Bu)2]Ge 1 yielded bis(alkylchalcogeno)germanes Me2Si(Nt-Bu)2Ge(ER)2 (R = Et, E = S 2, Se 3; R = Me, E = Se 4) and digermanes [Me2Si(Nt-Bu)2Ge(EEt)]2 (E = S 5, Se 6). The reaction of 1 with Et2Te2 proceeds with formation of Me2Si(Nt-Bu)2Ge(TeEt)27, which slowly converts into the Te-bridged complex [Me2Si(Nt-Bu)2GeTe]28. 1–6 and 8 were characterized by single crystal X-ray diffraction.

Graphical abstract: Germane vs. digermane formation

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Supplementary files

Article information


Submitted
07 Oct 2014
Accepted
10 Oct 2014
First published
17 Oct 2014

This article is Open Access

Chem. Commun., 2014,50, 15461-15463
Article type
Communication

Germane vs. digermane formation

P. Steiniger, G. Bendt, D. Bläser, C. Wölper and S. Schulz, Chem. Commun., 2014, 50, 15461
DOI: 10.1039/C4CC07921C

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