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Issue 95, 2014
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Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’

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Abstract

The use of a previously unexplored Schiff-base ligand in Ni(II) carboxylate chemistry has afforded a Ni26 cluster with a record nuclearity that crystallizes with a unique ‘rabbit-face’-like topology, and a Ni18 compound that adopts an unusual ‘molecular chain’ structure.

Graphical abstract: Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’

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Publication details

The article was received on 11 Sep 2014, accepted on 09 Oct 2014 and first published on 09 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC07192A
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Citation: Chem. Commun., 2014,50, 14942-14945

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    Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’

    A. A. Athanasopoulou, M. Pilkington, C. P. Raptopoulou, A. Escuer and T. C. Stamatatos, Chem. Commun., 2014, 50, 14942
    DOI: 10.1039/C4CC07192A

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