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Issue 95, 2014
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Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’

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Abstract

The use of a previously unexplored Schiff-base ligand in Ni(II) carboxylate chemistry has afforded a Ni26 cluster with a record nuclearity that crystallizes with a unique ‘rabbit-face’-like topology, and a Ni18 compound that adopts an unusual ‘molecular chain’ structure.

Graphical abstract: Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’

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Article information


Submitted
11 Sep 2014
Accepted
09 Oct 2014
First published
09 Oct 2014

Chem. Commun., 2014,50, 14942-14945
Article type
Communication
Author version available

Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’

A. A. Athanasopoulou, M. Pilkington, C. P. Raptopoulou, A. Escuer and T. C. Stamatatos, Chem. Commun., 2014, 50, 14942
DOI: 10.1039/C4CC07192A

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