From the interplay of high-resolution scanning tunneling microscopy (STM) imaging/manipulation and density functional theory (DFT) calculations, we have shown that the spontaneous formation of an organometallic complex by copper–alkene interactions can be successfully achieved, where the specific molecular adsorption geometry is revealed to be the key for facilitating such interaction.
C. Zhang, Q. Sun, H. Kong, L. Wang, Q. Tan and W. Xu, Chem. Commun., 2014, 50, 15924 DOI: 10.1039/C4CC06925K
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