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Issue 25, 2015
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Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

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Abstract

Chemical reduction of a tripodal Cu(II)–F complex containing pendent hydroxyl groups results in the partial dissociation of a F ligand from Cu. The resulting Cu(I) complex is characterized as containing an outer sphere F anion ‘captured’ by hydrogen bonds. The pendent hydroxyl groups were found to be crucial for reductive stability.

Graphical abstract: Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

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Supplementary files

Article information


Submitted
29 Aug 2014
Accepted
28 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2015,51, 5490-5492
Article type
Communication
Author version available

Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

C. M. Moore and N. K. Szymczak, Chem. Commun., 2015, 51, 5490
DOI: 10.1039/C4CC06832G

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