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Issue 4, 2015
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Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

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Abstract

Organomagnesium reagents enable swift and versatile derivatisation of diarylimines to the corresponding α-substituted diarylmethylamines in excellent yields, through fast and clean reactions. Where it occurs, 1,2-reduction can be circumvented using readily accessible dialkylmagnesium reagents.

Graphical abstract: Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

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Publication details

The article was received on 26 Aug 2014, accepted on 13 Nov 2014 and first published on 13 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC06719C
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Citation: Chem. Commun., 2015,51, 703-706

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    Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

    A. Desmarchelier, P. Ortiz and S. R. Harutyunyan, Chem. Commun., 2015, 51, 703
    DOI: 10.1039/C4CC06719C

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