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Issue 81, 2014
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Room temperature hydrophosphination using a simple iron salen pre-catalyst

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Abstract

Phosphines are fundamentally important to the fine chemicals, pharmaceutical and agrochemical industries. Reported is the first example of alkene hydrophosphination using a designed iron pre-catalyst which yields the anti-Markovnikov products in high yield at room temperature. The phosphine products are excellent pro-ligands for Fe-catalyzed Negishi cross-coupling.

Graphical abstract: Room temperature hydrophosphination using a simple iron salen pre-catalyst

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Supplementary files

Article information


Submitted
31 Jul 2014
Accepted
20 Aug 2014
First published
20 Aug 2014

Chem. Commun., 2014,50, 12109-12111
Article type
Communication
Author version available

Room temperature hydrophosphination using a simple iron salen pre-catalyst

K. J. Gallagher and R. L. Webster, Chem. Commun., 2014, 50, 12109
DOI: 10.1039/C4CC06526C

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