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Issue 95, 2014
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Morphological self-assembly of enantiopure allenes for upstanding chiral architectures at interfaces

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Abstract

Chiroptically active allenes are employed for the construction of surface-confined nanostructures. Morphological complementarity between the homochiral units leads to self-assembly of two highly-ordered, upstanding, diastereomeric architectures. The novel, intertwined self-assembled layer structures feature reactive terminal alkynes for further functionalization and carry potential for widespread applications exploiting chiroptical amplification.

Graphical abstract: Morphological self-assembly of enantiopure allenes for upstanding chiral architectures at interfaces

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Publication details

The article was received on 15 Aug 2014, accepted on 03 Oct 2014 and first published on 07 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC06398H
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Citation: Chem. Commun., 2014,50, 15022-15025
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    Morphological self-assembly of enantiopure allenes for upstanding chiral architectures at interfaces

    Y. Zhang, M. A. Öner, I. R. Lahoz, B. Cirera, C. Palma, S. Castro-Fernández, S. Míguez-Lago, M. M. Cid, J. V. Barth, J. L. Alonso-Gómez and F. Klappenberger, Chem. Commun., 2014, 50, 15022
    DOI: 10.1039/C4CC06398H

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