Issue 87, 2014
From the journal:

Chemical Communications

Multiple CH⋯O interactions involving glycol chains as driving force for the self-assembly of amphiphilic Pd(ii) complexes†

Christina Rest,a   Anja Martin,a   Vladimir Stepanenko,a   Naveen Kumar Allampally,a   David Schmidta  and  Gustavo Fernández*a  

* Corresponding authors

a Institut für Organische Chemie and Center for Nanosystems Chemistry, Universität Würzburg Am Hubland, 97074 Würzburg, Germany
E-mail: gustavo.fernandez@uni-wuerzburg.de

Abstract

We demonstrate that the self-assembly in polar media and gelation of an amphiphilic Pd(II) complex with pendant chlorine ligands are governed by cooperative intra- and interstrand CH⋯O interactions between peripheral triethylene glycol chains leading to slipped π-stacks.

Graphical abstract: Multiple CH⋯O interactions involving glycol chains as driving force for the self-assembly of amphiphilic Pd(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C4CC06152G
Article type
Communication
Submitted
06 Aug 2014
Accepted
10 Sep 2014
First published
10 Sep 2014

Chem. Commun., 2014,50, 13366-13369

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Multiple CH⋯O interactions involving glycol chains as driving force for the self-assembly of amphiphilic Pd(II) complexes

C. Rest, A. Martin, V. Stepanenko, N. K. Allampally, D. Schmidt and G. Fernández, Chem. Commun., 2014, 50, 13366 DOI: 10.1039/C4CC06152G

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