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Issue 87, 2014
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Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

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Abstract

Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

Graphical abstract: Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

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Article information


Submitted
06 Aug 2014
Accepted
08 Sep 2014
First published
08 Sep 2014

Chem. Commun., 2014,50, 13292-13295
Article type
Communication
Author version available

Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

H. H.-M. Yeung, M. Kosa, J. M. Griffin, C. P. Grey, D. T. Major and A. K. Cheetham, Chem. Commun., 2014, 50, 13292
DOI: 10.1039/C4CC06136E

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