Synthesis and crystal structure of a dinuclear, monomeric MnIIp-semiquinonato complex

Harutaka Nakamori; Takahiro Matsumoto; Takeshi Yatabe; Ki-Seok Yoon; Hidetaka Nakai; Seiji Ogo

doi:10.1039/C4CC06055E

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Synthesis and crystal structure of a dinuclear, monomeric Mn^IIp-semiquinonato complex†

Harutaka Nakamori,^ab Takahiro Matsumoto,^abc Takeshi Yatabe,^abc Ki-Seok Yoon,^ac Hidetaka Nakai^ab and Seiji Ogo*^abc

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* Corresponding authors

^a Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: ogo.seiji.872@m.kyushu-u.ac.jp
Fax: +81-92-802-2823
Tel: +81-92-802-2818

^b Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

^c International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Herein, we report the first crystal structure of a monomeric p-semiquinonato d-block complex and its reactivity toward dioxygen, closely associated with a biological system of an oxygen evolving centre of photosystem II.

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Article information

DOI: https://doi.org/10.1039/C4CC06055E
Article type: Communication
Submitted: 02 Aug 2014
Accepted: 02 Sep 2014
First published: 15 Sep 2014

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Chem. Commun., 2014,50, 13059-13061

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Synthesis and crystal structure of a dinuclear, monomeric Mn^IIp-semiquinonato complex

H. Nakamori, T. Matsumoto, T. Yatabe, K. Yoon, H. Nakai and S. Ogo, Chem. Commun., 2014, 50, 13059 DOI: 10.1039/C4CC06055E

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Chemical Communications