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Issue 91, 2014
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A high rotational barrier for physisorbed hydrogen in an fcu-metal–organic framework

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Abstract

A combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal–organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption.

Graphical abstract: A high rotational barrier for physisorbed hydrogen in an fcu-metal–organic framework

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Article information


Submitted
04 Aug 2014
Accepted
24 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2014,50, 14109-14112
Article type
Communication

A high rotational barrier for physisorbed hydrogen in an fcu-metal–organic framework

T. Pham, K. A. Forrest, P. A. Georgiev, W. Lohstroh, D. Xue, A. Hogan, M. Eddaoudi, B. Space and J. Eckert, Chem. Commun., 2014, 50, 14109
DOI: 10.1039/C4CC05987E

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