Issue 87, 2014

A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

Abstract

We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.

Graphical abstract: A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

Supplementary files

Article information

Article type
Communication
Submitted
30 Jul 2014
Accepted
09 Sep 2014
First published
19 Sep 2014

Chem. Commun., 2014,50, 13385-13387

A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

N. T. Nguyen, Y. Mori, T. Matsumoto, T. Yatabe, R. Kabe, H. Nakai, K. Yoon and S. Ogo, Chem. Commun., 2014, 50, 13385 DOI: 10.1039/C4CC05911E

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