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Issue 77, 2014
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Trapping atmospheric CO2 with gold

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Abstract

The ability of gold-hydroxides to fix CO2 is reported. [Au(IPr)(OH)] and [{Au(IPr)}2(μ-OH)][BF4] react with atmospheric CO2 to form the trigold carbonate complex [{Au(IPr)}33-CO3)][BF4]. Reactivity studies revealed that this complex behaves as two basic and one cationic Au centres, and that it is catalytically active. DFT calculations and kinetic experiments have been carried out.

Graphical abstract: Trapping atmospheric CO2 with gold

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Article information


Submitted
29 Jul 2014
Accepted
07 Aug 2014
First published
07 Aug 2014

Chem. Commun., 2014,50, 11321-11324
Article type
Communication
Author version available

Trapping atmospheric CO2 with gold

A. Collado, A. Gómez-Suárez, P. B. Webb, H. Kruger, M. Bühl, D. B. Cordes, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2014, 50, 11321
DOI: 10.1039/C4CC05910G

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