Issue 83, 2014
From the journal:

Chemical Communications

Formal synthesis of kingianin A based upon a novel electrochemically-induced radical cation Diels–Alder reaction†

Jonathan C. Moore, ORCID logo a   E. Stephen Davies,a   Darren A. Walsh,a   Pallavi Sharmaab  and  John E. Moses*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 1RD, UK
E-mail: john.moses@nottingham.ac.uk
Fax: +44 (0)115 951 3564
Tel: +44 (0)115 951 3533

b School of Chemistry, University of Lincoln, LN6 7TS, UK

Abstract

The application of electrochemical reactions in natural product synthesis has burgeoned in recent years. We herein report a formal synthesis of the complex and dimeric natural product kingianin A, which employs an electrochemically-mediated radical cation Diels–Alder cycloaddition as the key step.

Graphical abstract: Formal synthesis of kingianin A based upon a novel electrochemically-induced radical cation Diels–Alder reaction

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Article information

DOI
https://doi.org/10.1039/C4CC05906A
Article type
Communication
Submitted
29 Jul 2014
Accepted
29 Aug 2014
First published
08 Sep 2014

Chem. Commun., 2014,50, 12523-12525

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Formal synthesis of kingianin A based upon a novel electrochemically-induced radical cation Diels–Alder reaction

J. C. Moore, E. S. Davies, D. A. Walsh, P. Sharma and J. E. Moses, Chem. Commun., 2014, 50, 12523 DOI: 10.1039/C4CC05906A

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