A highly regio- and stereoselective (up to 99/1) nitro-oxoamination reaction of mono-substituted allene occurs under mild conditions with readily available AgNO2 and a free radical trap TEMPO to form one C–N bond and one C–O bond in one step. Various functional groups and heterocycles could be tolerated in this conversion.
C. Xue, C. Fu and S. Ma, Chem. Commun., 2014, 50, 15333 DOI: 10.1039/C4CC05743K
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