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Issue 1, 2015
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Post-assembly transformations of porphyrin-containing metal–organic framework (MOF) films fabricated via automated layer-by-layer coordination

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Abstract

Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

Graphical abstract: Post-assembly transformations of porphyrin-containing metal–organic framework (MOF) films fabricated via automated layer-by-layer coordination

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Publication details

The article was received on 24 Jul 2014, accepted on 13 Oct 2014 and first published on 17 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC05727A
Citation: Chem. Commun., 2015,51, 85-88

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    Post-assembly transformations of porphyrin-containing metal–organic framework (MOF) films fabricated via automated layer-by-layer coordination

    M. C. So, M. H. Beyzavi, R. Sawhney, O. Shekhah, M. Eddaoudi, S. S. Al-Juaid, J. T. Hupp and O. K. Farha, Chem. Commun., 2015, 51, 85
    DOI: 10.1039/C4CC05727A

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