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Issue 94, 2014
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A single-chain magnet based on linear [MnIII2MnII] units

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Abstract

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn–carboxylate SCM with a linear architecture.

Graphical abstract: A single-chain magnet based on linear [MnIII2MnII] units

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Supplementary files

Article information


Submitted
22 Jul 2014
Accepted
19 Sep 2014
First published
30 Sep 2014

This article is Open Access

Chem. Commun., 2014,50, 14873-14876
Article type
Communication
Author version available

A single-chain magnet based on linear [MnIII2MnII] units

C. Papatriantafyllopoulou, S. Zartilas, M. J. Manos, C. Pichon, R. Clérac and A. J. Tasiopoulos, Chem. Commun., 2014, 50, 14873
DOI: 10.1039/C4CC05687F

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