Issue 89, 2014

A 2D azine-linked covalent organic framework for gas storage applications

Abstract

A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g−1 of CO2, 9.9 mg g−1 of H2, and 11.5 mg g−1 of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.

Graphical abstract: A 2D azine-linked covalent organic framework for gas storage applications

Supplementary files

Article information

Article type
Communication
Submitted
22 Jul 2014
Accepted
18 Sep 2014
First published
18 Sep 2014

Chem. Commun., 2014,50, 13825-13828

Author version available

A 2D azine-linked covalent organic framework for gas storage applications

Z. Li, X. Feng, Y. Zou, Y. Zhang, H. Xia, X. Liu and Y. Mu, Chem. Commun., 2014, 50, 13825 DOI: 10.1039/C4CC05665E

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