Issue 85, 2014
From the journal:

Chemical Communications

Selective difluoroalkylation of alkenes by using visible light photoredox catalysis†

Chunghyeon Yu,a   Naeem Iqbal,a   Sehyun Parka  and  Eun Jin Cho*a  

* Corresponding authors

a Department of Bionanotechnology and Department of Applied Chemistry, Hanyang University, Republic of Korea
E-mail: echo@hanyang.ac.kr
Fax: +82-31-400-5457
Tel: +82-31-400-5496

Abstract

A visible light-induced process for selective difluoroalkylation of unactivated alkenes has been developed. The choice of base is crucial for governing the chemoselectivity of the process to produce difluoroalkylated alkanes and alkenes.

Graphical abstract: Selective difluoroalkylation of alkenes by using visible light photoredox catalysis

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Article information

DOI
https://doi.org/10.1039/C4CC05467A
Article type
Communication
Submitted
16 Jul 2014
Accepted
30 Aug 2014
First published
03 Sep 2014

Chem. Commun., 2014,50, 12884-12887

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Selective difluoroalkylation of alkenes by using visible light photoredox catalysis

C. Yu, N. Iqbal, S. Park and E. J. Cho, Chem. Commun., 2014, 50, 12884 DOI: 10.1039/C4CC05467A

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