Jump to main content
Jump to site search

Issue 85, 2014
Previous Article Next Article

SmI2–H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades

Author affiliations

Abstract

The SmI2H2O reagent system mediates challenging 5-exo/6-exo lactone radical cascade cyclisations that deliver carbo[5.4.0]bicyclic motifs in a diastereoselective, one-pot process that establish two new carbocyclic rings and four stereocentres.

Graphical abstract: SmI2–H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 Jul 2014, accepted on 15 Aug 2014 and first published on 15 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05404K
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2014,50, 12863-12866
  •   Request permissions

    SmI2–H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades

    I. Yalavac, S. E. Lyons, M. R. Webb and D. J. Procter, Chem. Commun., 2014, 50, 12863
    DOI: 10.1039/C4CC05404K

Search articles by author

Spotlight

Advertisements