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Issue 85, 2014
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SmI2–H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades

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Abstract

The SmI2H2O reagent system mediates challenging 5-exo/6-exo lactone radical cascade cyclisations that deliver carbo[5.4.0]bicyclic motifs in a diastereoselective, one-pot process that establish two new carbocyclic rings and four stereocentres.

Graphical abstract: SmI2–H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades

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Article information


Submitted
14 Jul 2014
Accepted
15 Aug 2014
First published
15 Aug 2014

Chem. Commun., 2014,50, 12863-12866
Article type
Communication
Author version available

SmI2–H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades

I. Yalavac, S. E. Lyons, M. R. Webb and D. J. Procter, Chem. Commun., 2014, 50, 12863
DOI: 10.1039/C4CC05404K

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