Probing the role of an FeIV tetrazene in catalytic aziridination

S. Alan Cramer; Raúl Hernández Sánchez; Desirae F. Brakhage; David M. Jenkins

doi:10.1039/C4CC05124F

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Probing the role of an Fe^IV tetrazene in catalytic aziridination†

S. Alan Cramer,^a Raúl Hernández Sánchez,^b Desirae F. Brakhage^a and David M. Jenkins*^a

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* Corresponding authors

^a Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, USA
E-mail: jenkins@ion.chem.utk.edu

^b Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts, USA

Abstract

An iron(IV) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(IV) imide is formed and this imide can bind an additional ligand in the cis position.

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Article information

DOI: https://doi.org/10.1039/C4CC05124F
Article type: Communication
Submitted: 03 Jul 2014
Accepted: 09 Sep 2014
First published: 30 Sep 2014

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Chem. Commun., 2014,50, 13967-13970

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Probing the role of an Fe^IV tetrazene in catalytic aziridination

S. A. Cramer, R. Hernández Sánchez, D. F. Brakhage and D. M. Jenkins, Chem. Commun., 2014, 50, 13967 DOI: 10.1039/C4CC05124F

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