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Issue 90, 2014
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Probing the role of an FeIV tetrazene in catalytic aziridination

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Abstract

An iron(IV) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(IV) imide is formed and this imide can bind an additional ligand in the cis position.

Graphical abstract: Probing the role of an FeIV tetrazene in catalytic aziridination

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Article information


Submitted
03 Jul 2014
Accepted
09 Sep 2014
First published
30 Sep 2014

Chem. Commun., 2014,50, 13967-13970
Article type
Communication

Probing the role of an FeIV tetrazene in catalytic aziridination

S. A. Cramer, R. Hernández Sánchez, D. F. Brakhage and D. M. Jenkins, Chem. Commun., 2014, 50, 13967
DOI: 10.1039/C4CC05124F

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