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Issue 82, 2014
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Sequential Bi–C bond activation reactions of BiEt3via insertion reactions of RE {R = HC[C(Me)N(2,6-i-Pr2C6H3)]2; E = Al, Ga, In}

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Abstract

Two of the Bi–C bonds of BiEt3 are sequentially activated by mono-valent RM {R = HC[C(Me)N(2,6-i-Pr2C6H3)]2; M = Al, Ga, In}. The first Bi–C bond activation leads to the formation of insertion complexes, [RMEt(BiEt2)] (M = Al 1; Ga 2; In 3), whereas the consecutive second activation proceeds through a reductive elimination of RMEt2 (M = Al 4, Ga 5), elemental Bi and BiEt3.

Graphical abstract: Sequential Bi–C bond activation reactions of BiEt3via insertion reactions of RE {R = HC[C(Me)N(2,6-i-Pr2C6H3)]2; E = Al, Ga, In}

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Supplementary files

Article information


Submitted
01 Jul 2014
Accepted
23 Aug 2014
First published
27 Aug 2014

This article is Open Access

Chem. Commun., 2014,50, 12382-12384
Article type
Communication

Sequential Bi–C bond activation reactions of BiEt3via insertion reactions of RE {R = HC[C(Me)N(2,6-i-Pr2C6H3)]2; E = Al, Ga, In}

C. Ganesamoorthy, D. Bläser, C. Wölper and S. Schulz, Chem. Commun., 2014, 50, 12382
DOI: 10.1039/C4CC05028B

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