Ion-based assemblies of planar anion complexes and cationic PtII complexes

Ryo Sekiya; Yusuke Tsutsui; Wookjin Choi; Tsuneaki Sakurai; Shu Seki; Yuya Bando; Hiromitsu Maeda

doi:10.1039/C4CC04565C

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Ion-based assemblies of planar anion complexes and cationic Pt^II complexes†

Ryo Sekiya,‡^a Yusuke Tsutsui,^b Wookjin Choi,^b Tsuneaki Sakurai,^b Shu Seki,*^b Yuya Bando^a and Hiromitsu Maeda*^a

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* Corresponding authors

^a College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu 525–8577, Japan
E-mail: maedahir@ph.ritsumei.ac.jp

^b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565–0871, Japan
E-mail: seki@chem.eng.osaka-u.ac.jp

Abstract

Because the metallophilicity of attractive Pt^II⋯Pt^II interactions helps in the fabrication of columnar structures, terpyridine–Pt^II complexes were used as planar counter cationic species for formation of charge-segregated assemblies using π-conjugated receptor–Cl⁻ complexes as planar anions.

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Article information

DOI: https://doi.org/10.1039/C4CC04565C
Article type: Communication
Submitted: 16 Jun 2014
Accepted: 14 Jul 2014
First published: 23 Jul 2014

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Chem. Commun., 2014,50, 10615-10618

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Ion-based assemblies of planar anion complexes and cationic Pt^II complexes

R. Sekiya, Y. Tsutsui, W. Choi, T. Sakurai, S. Seki, Y. Bando and H. Maeda, Chem. Commun., 2014, 50, 10615 DOI: 10.1039/C4CC04565C

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Chemical Communications