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Issue 79, 2014
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The use of a well-defined surface organometallic complex as a probe molecule: [([triple bond, length as m-dash]SiO)TaVCl2Me2] shows different isolated silanol sites on the silica surface

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Abstract

TaVCl2Me3 reacts with silica(700) and produces two different [([triple bond, length as m-dash]SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach.

Graphical abstract: The use of a well-defined surface organometallic complex as a probe molecule: [( [[triple bond, length as m-dash]] SiO)TaVCl2Me2] shows different isolated silanol sites on the silica surface

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Article information


Submitted
04 Jun 2014
Accepted
14 Aug 2014
First published
14 Aug 2014

Chem. Commun., 2014,50, 11721-11723
Article type
Communication
Author version available

The use of a well-defined surface organometallic complex as a probe molecule: [([triple bond, length as m-dash]SiO)TaVCl2Me2] shows different isolated silanol sites on the silica surface

Y. Chen, B. Zheng, E. Abou-Hamad, A. Hamieh, B. Hamzaoui, K. Huang and J. Basset, Chem. Commun., 2014, 50, 11721
DOI: 10.1039/C4CC04277H

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