Organic–inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium have been developed. They display two well-separated redox couples at low potentials. Each of the three readily accessible oxidation states can be distinguished by the absorbance at three different wavelengths.
H. Nie, J. Shao, C. Yao and Y. Zhong, Chem. Commun., 2014, 50, 10082 DOI: 10.1039/C4CC04268A
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