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Issue 67, 2014
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Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

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Abstract

The Pd/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.

Graphical abstract: Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

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Article information


Submitted
22 May 2014
Accepted
04 Jul 2014
First published
04 Jul 2014

Chem. Commun., 2014,50, 9550-9553
Article type
Communication
Author version available

Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

B. Feng, H. Cheng, J. Chen, Q. Deng, L. Lu and W. Xiao, Chem. Commun., 2014, 50, 9550
DOI: 10.1039/C4CC03920C

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