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Issue 66, 2014
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4-Halogeno-sydnones for fast strain promoted cycloaddition with bicyclo-[6.1.0]-nonyne

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Abstract

New sydnone derivatives have been synthesized and screened for their capacity to undergo fast copper-free cycloaddition reaction with bicyclo-[6.1.0]-nonyne. The influences of substitution in positions N-3 and C-4 of sydnones have been particularly studied leading to the identification of highly reactive partners for bio-orthogonal ligation reactions.

Graphical abstract: 4-Halogeno-sydnones for fast strain promoted cycloaddition with bicyclo-[6.1.0]-nonyne

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Article information


Submitted
19 May 2014
Accepted
13 Jun 2014
First published
30 Jun 2014

Chem. Commun., 2014,50, 9376-9378
Article type
Communication
Author version available

4-Halogeno-sydnones for fast strain promoted cycloaddition with bicyclo-[6.1.0]-nonyne

L. Plougastel, O. Koniev, S. Specklin, E. Decuypere, C. Créminon, D. Buisson, A. Wagner, S. Kolodych and F. Taran, Chem. Commun., 2014, 50, 9376
DOI: 10.1039/C4CC03816A

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