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Side chain engineering of an n-type polymer provides a means of maintaining solubility while increasing crystallinity and electron mobility, leading to enhanced photocurrent. Bulk heterojunction solar cells composed of a side chain engineered copolymer (PNDIS-30BO) as acceptor and PSEHTT as donor give 10.4 mA cm−2 photocurrent and 4.4% efficiency.

Graphical abstract: Side chain engineering of n-type conjugated polymer enhances photocurrent and efficiency of all-polymer solar cells

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