Issue 93, 2014
From the journal:

Chemical Communications

Visible-light-enhanced Suzuki–Miyaura coupling reaction by cooperative photocatalysis with an Ru–Pd bimetallic complex†

Kohsuke Mori,*ab   Masayoshi Kawashimaa  and  Hiromi Yamashita*ab  

* Corresponding authors

a Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: mori@mat.eng.osaka-u.ac.jp, yamashita@mat.eng.osaka-u.ac.jp
Fax: +81-6-6879-7457
Tel: +81-6-6879-7457

b Unit of Elements Strategy Initiative for Catalysts & Batteries, Kyoto University, Katsura, Kyoto 615-8520, Japan

Abstract

A photo-assisted Suzuki–Miyaura coupling reaction has been realized by a molecule Pd(II) complex containing a Ru(II)-polypyridyl derivative as a visible light photosensitizing unit, where an electron transfer from excited Ru species to Pd forms an active electron rich Pd(0) and facilitates the oxidative addition step with aryl halides.

Graphical abstract: Visible-light-enhanced Suzuki–Miyaura coupling reaction by cooperative photocatalysis with an Ru–Pd bimetallic complex

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Article information

DOI
https://doi.org/10.1039/C4CC03682D
Article type
Communication
Submitted
15 May 2014
Accepted
10 Jun 2014
First published
10 Jun 2014

Chem. Commun., 2014,50, 14501-14503

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Visible-light-enhanced Suzuki–Miyaura coupling reaction by cooperative photocatalysis with an Ru–Pd bimetallic complex

K. Mori, M. Kawashima and H. Yamashita, Chem. Commun., 2014, 50, 14501 DOI: 10.1039/C4CC03682D

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