Jump to main content
Jump to site search

Issue 87, 2014
Previous Article Next Article

Alkyne mechanochemistry: putative activation by transoidal bending

Author affiliations

Abstract

We investigated the use of mechanical stress to bend carbon–carbon triple bonds. Formation of an isoquinoline after reaction with a benzyl azide trap points towards a nucleophilic addition mechanism, differentiating mechanochemical trans-bending of π bonds from the typical reactivity observed for cisoidal bending of triple bonds in strained cyclic alkynes.

Graphical abstract: Alkyne mechanochemistry: putative activation by transoidal bending

Back to tab navigation

Supplementary files

Article information


Submitted
09 May 2014
Accepted
30 Jul 2014
First published
30 Jul 2014

Chem. Commun., 2014,50, 13235-13238
Article type
Communication
Author version available

Alkyne mechanochemistry: putative activation by transoidal bending

C. E. Diesendruck, L. Zhu and J. S. Moore, Chem. Commun., 2014, 50, 13235
DOI: 10.1039/C4CC03514C

Social activity

Search articles by author

Spotlight

Advertisements