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Issue 69, 2014
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Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

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Abstract

Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph, –SC6H13, and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2 reduction.

Graphical abstract: Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

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Publication details

The article was received on 07 May 2014, accepted on 26 Jun 2014 and first published on 16 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03424D
Chem. Commun., 2014,50, 9895-9898

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    Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

    V. R. Jupally, A. C. Dharmaratne, D. Crasto, A. J. Huckaba, C. Kumara, P. R. Nimmala, N. Kothalawala, J. H. Delcamp and A. Dass, Chem. Commun., 2014, 50, 9895
    DOI: 10.1039/C4CC03424D

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