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Issue 69, 2014
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Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

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Abstract

Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph, –SC6H13, and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2 reduction.

Graphical abstract: Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

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Article information


Submitted
07 May 2014
Accepted
26 Jun 2014
First published
16 Jul 2014

Chem. Commun., 2014,50, 9895-9898
Article type
Communication

Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

V. R. Jupally, A. C. Dharmaratne, D. Crasto, A. J. Huckaba, C. Kumara, P. R. Nimmala, N. Kothalawala, J. H. Delcamp and A. Dass, Chem. Commun., 2014, 50, 9895
DOI: 10.1039/C4CC03424D

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