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Issue 60, 2014
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A plutonium-based single-molecule magnet

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Abstract

The magnetic properties of the 5f5 [tris-(tri-1-pyrazolylborato)–plutonium(III)] complex have been investigated by ac susceptibility measurements, showing it to be the first plutonium single-molecule magnet; its magnetic relaxation slows down with decreasing temperature through a thermally activated mechanism followed by a quantum tunnelling regime below 5 K.

Graphical abstract: A plutonium-based single-molecule magnet

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Supplementary files

Article information


Submitted
06 May 2014
Accepted
09 Jun 2014
First published
11 Jun 2014

Chem. Commun., 2014,50, 8171-8173
Article type
Communication

A plutonium-based single-molecule magnet

N. Magnani, E. Colineau, J.-C. Griveau, C. Apostolidis, O. Walter and R. Caciuffo, Chem. Commun., 2014, 50, 8171
DOI: 10.1039/C4CC03400G

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