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The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B[double bond, length as m-dash]O double-bond property.

Graphical abstract: 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid

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