Issue 70, 2014
From the journal:

Chemical Communications

Organometallic macromolecules with piano stool coordination repeating units: chain configuration and stimulated solution behaviour†

Kai Cao,a   Jonathan Ward,b   Ryan C. Amos,a   Moon Gon Jeong,c   Kyoung Taek Kim,c   Mario Gauthier,a   Daniel Foucher*b  and  Xiaosong Wang*a  

* Corresponding authors

a Department of Chemistry and Waterloo Institute for Nanothechnology (WIN), University of Waterloo, 200 University Ave, Waterloo, N2L 3G1, Canada
E-mail: xiaosong.wang@uwaterloo.ca

b Department of Chemistry and Biology, Ryerson University, 350 Victoria Street, Toronto, M5B 2K3, Canada
E-mail: daniel.foucher@ryerson.ca

c Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798, Korea
E-mail: ktkim@unist.ac.kr

Abstract

Theoretical calculations illustrate that organometallic macromolecules with piano stool coordination repeating units (Fe-acyl complex) adopt linear chain configuration with a P–Fe–C backbone surrounded by aromatic groups. The macromolecules show molecular weight-dependent and temperature stimulated solution behaviour in DMSO.

Graphical abstract: Organometallic macromolecules with piano stool coordination repeating units: chain configuration and stimulated solution behaviour

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Article information

DOI
https://doi.org/10.1039/C4CC03064H
Article type
Communication
Submitted
24 Apr 2014
Accepted
10 Jul 2014
First published
10 Jul 2014

Chem. Commun., 2014,50, 10062-10065

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Organometallic macromolecules with piano stool coordination repeating units: chain configuration and stimulated solution behaviour

K. Cao, J. Ward, R. C. Amos, M. G. Jeong, K. T. Kim, M. Gauthier, D. Foucher and X. Wang, Chem. Commun., 2014, 50, 10062 DOI: 10.1039/C4CC03064H

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