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Issue 51, 2014
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Diastereo- and enantioselective synthesis of 1,3,5,7-tetraol structural units using a Prins cyclisation–reductive cleavage sequence

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Abstract

Stereocontrolled and efficient access to all the diastereomers of 1,3,5,7-tetraol structural units was developed using a Prins cyclisation–reductive cleavage sequence applied to tetrahydropyran aldehydes. Furthermore, these tetraols can be selectively functionalized.

Graphical abstract: Diastereo- and enantioselective synthesis of 1,3,5,7-tetraol structural units using a Prins cyclisation–reductive cleavage sequence

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The article was received on 11 Apr 2014, accepted on 01 May 2014 and first published on 06 May 2014


Article type: Communication
DOI: 10.1039/C4CC02702G
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Chem. Commun., 2014,50, 6718-6721

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    Diastereo- and enantioselective synthesis of 1,3,5,7-tetraol structural units using a Prins cyclisation–reductive cleavage sequence

    E. Brun, V. Bellosta and J. Cossy, Chem. Commun., 2014, 50, 6718
    DOI: 10.1039/C4CC02702G

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