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Issue 51, 2014
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Diastereo- and enantioselective synthesis of 1,3,5,7-tetraol structural units using a Prins cyclisation–reductive cleavage sequence

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Abstract

Stereocontrolled and efficient access to all the diastereomers of 1,3,5,7-tetraol structural units was developed using a Prins cyclisation–reductive cleavage sequence applied to tetrahydropyran aldehydes. Furthermore, these tetraols can be selectively functionalized.

Graphical abstract: Diastereo- and enantioselective synthesis of 1,3,5,7-tetraol structural units using a Prins cyclisation–reductive cleavage sequence

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Article information


Submitted
11 Apr 2014
Accepted
01 May 2014
First published
06 May 2014

Chem. Commun., 2014,50, 6718-6721
Article type
Communication
Author version available

Diastereo- and enantioselective synthesis of 1,3,5,7-tetraol structural units using a Prins cyclisation–reductive cleavage sequence

E. Brun, V. Bellosta and J. Cossy, Chem. Commun., 2014, 50, 6718
DOI: 10.1039/C4CC02702G

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