Jump to main content
Jump to site search

Issue 65, 2014
Previous Article Next Article

Synthesis and characterization of a new Keggin anion: [BeW12O40]6−

Author affiliations

Abstract

The first Keggin-type Be-containing heteropolyanion [BeW12O40]6− (16−) has been obtained by hydrothermal synthesis from sodium tungstate and Be(NO3)2. It was crystallized as (Bu4N)4.8Na1.2[BeW12O40] (1a) and (Me2NH2)6[BeW12O40]·4H2O (1b) salts, which were characterized by 9Be and 183W NMR, ESI-MS, CV, and single crystal X-ray diffraction analysis.

Graphical abstract: Synthesis and characterization of a new Keggin anion: [BeW12O40]6−

Back to tab navigation

Supplementary files

Article information


Submitted
03 Apr 2014
Accepted
23 Jun 2014
First published
24 Jun 2014

Chem. Commun., 2014,50, 9083-9085
Article type
Communication
Author version available

Synthesis and characterization of a new Keggin anion: [BeW12O40]6−

A. V. Anyushin, A. I. Smolentsev, D. A. Mainichev, C. Vicent, A. L. Gushchin, M. N. Sokolov and V. P. Fedin, Chem. Commun., 2014, 50, 9083
DOI: 10.1039/C4CC02456G

Social activity

Search articles by author

Spotlight

Advertisements