Jump to main content
Jump to site search

Issue 65, 2014
Previous Article Next Article

Synthesis and characterization of a new Keggin anion: [BeW12O40]6−

Author affiliations

Abstract

The first Keggin-type Be-containing heteropolyanion [BeW12O40]6− (16−) has been obtained by hydrothermal synthesis from sodium tungstate and Be(NO3)2. It was crystallized as (Bu4N)4.8Na1.2[BeW12O40] (1a) and (Me2NH2)6[BeW12O40]·4H2O (1b) salts, which were characterized by 9Be and 183W NMR, ESI-MS, CV, and single crystal X-ray diffraction analysis.

Graphical abstract: Synthesis and characterization of a new Keggin anion: [BeW12O40]6−

Back to tab navigation

Supplementary files

Publication details

The article was received on 03 Apr 2014, accepted on 23 Jun 2014 and first published on 24 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC02456G
Author version
available:
Download author version (PDF)
Chem. Commun., 2014,50, 9083-9085

  •   Request permissions

    Synthesis and characterization of a new Keggin anion: [BeW12O40]6−

    A. V. Anyushin, A. I. Smolentsev, D. A. Mainichev, C. Vicent, A. L. Gushchin, M. N. Sokolov and V. P. Fedin, Chem. Commun., 2014, 50, 9083
    DOI: 10.1039/C4CC02456G

Search articles by author

Spotlight

Advertisements