Reduction of CO2 to free CO by a Pd(I)–Pd(I) dimer

Chandra Mouli Palit; Daniel J. Graham; Chun-Hsing Chen; Bruce M. Foxman; Oleg V. Ozerov

doi:10.1039/C4CC02438A

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Reduction of CO₂ to free CO by a Pd(i)–Pd(i) dimer†

Chandra Mouli Palit,^a Daniel J. Graham,‡^b Chun-Hsing Chen,§^b Bruce M. Foxman^b and Oleg V. Ozerov*^a

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* Corresponding authors

^a Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, USA
E-mail: ozerov@chem.tamu.edu
Tel: +1 979 845 5870

^b Department of Chemistry, Brandeis University, MS015, 415 South Street, Waltham, Massachusetts 02454, USA

Abstract

Reaction of CO₂ with a Pd(I)–Pd(I) dimer supported by amido/bis(phosphine) pincer PNP ligands produces free CO in the presence of Me₃SiCl and Me₃SiOTf.

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Article information

DOI: https://doi.org/10.1039/C4CC02438A
Article type: Communication
Submitted: 02 Apr 2014
Accepted: 04 Jul 2014
First published: 07 Jul 2014

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Chem. Commun., 2014,50, 12840-12842

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Reduction of CO₂ to free CO by a Pd(I)–Pd(I) dimer

C. M. Palit, D. J. Graham, C. Chen, B. M. Foxman and O. V. Ozerov, Chem. Commun., 2014, 50, 12840 DOI: 10.1039/C4CC02438A

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