A new protocol for the synthesis of fully substituted enaminones has been achieved using a diverse range of benzamides and 1-sulfonyl-1,2,3-triazoles. Selective removal of the β-amino moiety of the obtained α-amido-enaminones to form Z-enamides was also demonstrated thus improving the synthetic value of benzamides for structural diversities in a minimum number of synthetic steps.
D. J. Lee, J. Shin and E. J. Yoo, Chem. Commun., 2014, 50, 6620 DOI: 10.1039/C4CC02155J
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