Issue 57, 2014
From the journal:

Chemical Communications

Electrochemical discrimination of phthalic acid among three phthalic acid isomers based on an N-butylaminomethyl-ferrocene derivative†

Jisoo Yoon,‡a   Jyoti Ramesh Jadhav,‡b   Jun Myung Kim,‡a   Minserk Cheong,a   Hong-Seok Kim*b  and  Joohoon Kim*a  

* Corresponding authors

a Department of Chemistry, Research Institute for Basic Sciences, Kyung Hee University, Seoul 130-701, Korea
E-mail: jkim94@khu.ac.kr

b Department of Applied Chemistry, Kyungpook National University, Daegu 702-701, Korea
E-mail: kimhs@knu.ac.kr

Abstract

A chemosensor compound (1) consisting of a central ferrocene with two butylaminomethyl arms showed unexpected facile electrochemical oxidation of the secondary amines in proximity to the ferrocene, which was utilized for electrochemical discrimination of phthalic acid selectively over two other isomers, isophthalic acid and terephthalic acid.

Graphical abstract: Electrochemical discrimination of phthalic acid among three phthalic acid isomers based on an N-butylaminomethyl-ferrocene derivative

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Article information

DOI
https://doi.org/10.1039/C4CC01659A
Article type
Communication
Submitted
05 Mar 2014
Accepted
27 May 2014
First published
27 May 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 7670-7672

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Electrochemical discrimination of phthalic acid among three phthalic acid isomers based on an N-butylaminomethyl-ferrocene derivative

J. Yoon, J. R. Jadhav, J. M. Kim, M. Cheong, H. Kim and J. Kim, Chem. Commun., 2014, 50, 7670 DOI: 10.1039/C4CC01659A

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