New members of layered oxychloride perovskites with square planar coordination: Sr2MO2Cl2 (M = Mn, Ni) and Ba2PdO2Cl2

Y. Tsujimoto; C. I. Sathish; Y. Matsushita; K. Yamaura; T. Uchikoshi

doi:10.1039/C4CC01422G

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New members of layered oxychloride perovskites with square planar coordination: Sr₂MO₂Cl₂ (M = Mn, Ni) and Ba₂PdO₂Cl₂†

Y. Tsujimoto,*^a C. I. Sathish,^b Y. Matsushita,^c K. Yamaura^b and T. Uchikoshi^a

Author affiliations

* Corresponding authors

^a Materials Processing Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
E-mail: TSUJIMOTO.Yoshihiro@nims.go.jp

^b Superconducting Properties Unit, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

^c Materials Analysis Station, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

Abstract

New members of Ruddlesden–Popper type layered oxychloride compounds, Sr₂MO₂Cl₂ (M = Mn, Ni) and Ba₂PdO₂Cl₂, were synthesized under high-pressure conditions. Synchrotron XRD analysis revealed that all the phases adopt the tetragonal space group I4/mmm, where two-dimensional sheets composed of corner-sharing MO₄/PdO₄ squares were separated by rock-salt SrCl/BaCl layers.

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Article information

DOI: https://doi.org/10.1039/C4CC01422G
Article type: Communication
Submitted: 24 Feb 2014
Accepted: 14 Apr 2014
First published: 14 Apr 2014

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Chem. Commun., 2014,50, 5915-5918

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New members of layered oxychloride perovskites with square planar coordination: Sr₂MO₂Cl₂ (M = Mn, Ni) and Ba₂PdO₂Cl₂

Y. Tsujimoto, C. I. Sathish, Y. Matsushita, K. Yamaura and T. Uchikoshi, Chem. Commun., 2014, 50, 5915 DOI: 10.1039/C4CC01422G

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