Issue 36, 2014
From the journal:

Chemical Communications

A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes†

Daniela Tapu,*a   Zachary McCartya  and  Colin McMillenb  

* Corresponding authors

a Department of Chemistry and Biochemistry, Kennesaw State University, 1000 Chastain Road, Kennesaw, GA, USA
E-mail: dtapu@kennesaw.edu
Fax: +1-770-423-6744
Tel: +1-678-797-2259

b X-ray Crystallography Laboratory, Department of Chemistry, Clemson University, Clemson, SC, USA

Abstract

The first stable dianionic Janus-type bis(maloNHC) was isolated and characterized. Details on the chemistry of this biscarbene with respect to its ability to support catalytically relevant metal complexes are provided. The molecular structures of two dinuclear gold and silver complexes were determined by X-ray crystallography.

Graphical abstract: A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

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Article information

DOI
https://doi.org/10.1039/C4CC01200C
Article type
Communication
Submitted
14 Feb 2014
Accepted
22 Mar 2014
First published
24 Mar 2014

Chem. Commun., 2014,50, 4725-4728

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A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

D. Tapu, Z. McCarty and C. McMillen, Chem. Commun., 2014, 50, 4725 DOI: 10.1039/C4CC01200C

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