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Issue 36, 2014
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A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

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Abstract

The first stable dianionic Janus-type bis(maloNHC) was isolated and characterized. Details on the chemistry of this biscarbene with respect to its ability to support catalytically relevant metal complexes are provided. The molecular structures of two dinuclear gold and silver complexes were determined by X-ray crystallography.

Graphical abstract: A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

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Article information


Submitted
14 Feb 2014
Accepted
22 Mar 2014
First published
24 Mar 2014

Chem. Commun., 2014,50, 4725-4728
Article type
Communication

A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

D. Tapu, Z. McCarty and C. McMillen, Chem. Commun., 2014, 50, 4725
DOI: 10.1039/C4CC01200C

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