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Issue 46, 2014
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Synthesis of isoquinolines via visible light-promoted insertion of vinyl isocyanides with diaryliodonium salts

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Abstract

A synthetic strategy for multi-substituted isoquinoline derivatives has been developed using visible light-promoted vinyl isocyanide insertion with diaryliodonium salts at room temperature. The methodology presented here represents the first example of isoquinoline synthesis via somophilic isocyanide insertion.

Graphical abstract: Synthesis of isoquinolines via visible light-promoted insertion of vinyl isocyanides with diaryliodonium salts

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Supplementary files

Article information


Submitted
12 Feb 2014
Accepted
14 Apr 2014
First published
15 Apr 2014

Chem. Commun., 2014,50, 6164-6167
Article type
Communication

Synthesis of isoquinolines via visible light-promoted insertion of vinyl isocyanides with diaryliodonium salts

H. Jiang, Y. Cheng, R. Wang, Y. Zhang and S. Yu, Chem. Commun., 2014, 50, 6164
DOI: 10.1039/C4CC01122H

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